ArticleChemical science2026
Dichroic dyes mediated mirrored full-color and white circularly polarized luminescence in natural cholesteric liquid crystal systems.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Natural chiral dopants have been widely employed in liquid crystal displays, biomedicine, and chiral optical materials owing to their easy availability of chirality and excellent biocompatibility. However, most natural chiral compounds exist exclusively as a single enantiomer, which severely restricts their application scope in circularly polarized luminescence (CPL). Herein, we design and synthesize a class of full-color dichroic dyes capable of modulating the handedness of CPL signals without relying on chiral dopants. In natural chiral dopant-incorporated cholesteric liquid crystal (CLC) systems, these dyes with a unique excited-state intramolecular proton transfer (ESIPT) isomeric structure achieve mirror-symmetric full-color and white CPL. This work expands the application of natural chiral compounds in CPL materials and provides a novel, sustainable strategy for high-performance CPL devices and flexible optical displays.
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