ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Efficient Osmotic Energy Conversion Enabled by Self-Standing COF Membranes With Varied Sulfonic Acid Group Density.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The Gibbs free energy generated from the mixing of seawater and freshwater across a salinity gradient is considered one of the most significant yet underutilized renewable energy sources. Membrane-based reverse electrodialysis (RED) enables direct electricity generation from osmotic energy by harnessing the net ion flux driven by concentration gradients across ion-selective membranes. However, entropy generation caused by non-selective ion mixing significantly limits the power density of RED systems. Therefore, enhancing membrane ion selectivity is critical. 2D covalent organic frameworks (COFs) demonstrate remarkable potential for osmotic energy conversion due to their aligned 1D nanochannel, high porosity, and organized ionic groups. Herein, we present a strategy leveraging electrostatic repulsion to controllably fabricate TpPa-(SO
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