ArticleNature communications2026
Enantioselective Electrocatalytic Hydrogenation of α,β-Unsaturated Esters and Allylic Alcohols.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Asymmetric electrocatalytic hydrogenation has long been of interest in the field of electrosynthesis. Nevertheless, explorations of highly enantioselective asymmetric electrocatalytic hydrogenation reactions are rare. Herein, we report the enantioselective electrocatalytic hydrogenation of conjugated olefins with high enantioselectivity. The catalyst precursor comprises cost-effective, earth-abundant nickel with a strongly σ-donating bis-phosphine (Me-DuPhos) ligand, and protons and electrons are used together directly as the hydrogen source. This strategy avoids the need for highly pressurized H
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