ArticleAngewandte Chemie (International ed. in English)2026
Dual-Affinity Interphase Engineering Enables Stable Aqueous Zn-S Batteries.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Aqueous Zn-S batteries have garnered significant attention for grid-scale storage but suffer from rapid capacity fade and sluggish reaction kinetics. Although existing strategies can improve redox reversibility, they fail to fundamentally address capacity attenuation arising from oxidation-driven ZnS decomposition loss. In this study, a nano-copper-based cathode/electrolyte interphase (Cu CEI) featuring a unique sulfur/ZnS dual-affinity is rationally designed to accelerate both S─S and Zn─S bond dynamics, effectively preventing ZnS accumulation and suppressing its decomposition via preferential Cu-ZnS binding. Specifically, the strong binding affinity of the Cu CEI stabilizes ZnS by reducing its direct contact with interfacial water. Meanwhile, the strong interaction between Cu nanoparticles and S
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