ArticleAngewandte Chemie (International ed. in English)2026
Synthesis of Uniform 6-Armchair Graphene Nanoribbons and Their Isotope and Nitrogen-Doped Derivatives.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
On-surface synthesis enables precision synthesis of graphene nanoribbons (GNRs), allowing for tailored edge structures and widths through engineered polymerization and dehydrocyclization of designed precursor molecules. Here, we report the successful transformation of various precursor molecules into uniform 0.6 nm-wide armchair GNRs encapsulated within carbon nanotubes or boron nitride nanotubes, facilitating large-scale production. Remarkably, our results show that not only aromatic hydrocarbon molecules with hexagonal structures, but also those containing pentagonal, heptagonal, or octagonal motifs yield uniform GNRs composed exclusively of hexagons. This impressive tolerance for diverse encapsulated molecules and host materials underscores the universality of our method. Additionally, we successfully synthesized 0.6 nm-wide deuterated,
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