ArticleThe journal of physical chemistry. A2026
Photochemistry of Sodium Pyruvate Clusters.
Article in The journal of physical chemistry. A, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Pyruvate is frequently found in aged sea salt aerosols. To test the influence of the salt environment on the photochemistry of pyruvate, small model clusters were generated from sodium pyruvate salt using electrospray ionization. These clusters were studied using Fourier-Transform Ion Cyclotron Resonance mass spectrometry (FT-ICR MS). UV/vis spectra were recorded using a tunable optical parametric oscillator (OPO) system. Additionally, photokinetics as well as sustained off-resonance irradiation (SORI) collision-induced dissociation (CID) experiments help to further understand the mechanisms responsible for the fragmentation of the studied systems. Quantum chemical calculations allow assignment of the transitions responsible for the absorptions. The clusters mainly fragment by losing sodium pyruvate units, Na
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