ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Harnessing N─H···O═V Bonding Toward Stable Vanadium Cathodes in Ah-Level Zn-Ion Batteries.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 authors.
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Abstract
The vanadium-based batteries deliver great potential in Ah-level energy storage systems, ascribing to their high specific capacity. Nevertheless, the metal-oxygen bonds are unstable in aqueous electrolytes, resulting in structural degradation and capacity attenuation. Here, inspired by the robust N─H···O═C bonding that stabilizes protein structures, we propose a bioinspired polymer-integrated electrolyte based on poly(N-acryloyl glycinamide) (PNAGA). The amide-rich N-H groups in PNAGA can anchor onto vanadium oxide units (O═V) via strong protein-like intermolecular N─H···O═V interactions, which effectively stabilize the cathode framework by suppressing vanadium dissolution and preserving structural integrity during Zn
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