ArticleAngewandte Chemie (International ed. in English)2026
Coordination-Driven Direct C─H Metalation of N-Heterocycles With a Superbasic Co(II) Amide Co(TMP)
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Metalation of N-heterocycles such as pyridines or diazines with conventional alkali metal bases is particularly challenging due to the limited activation of their C─H bonds coupled with the thermal fragility of the resulting organometallic intermediates. Building upon previous work in this area, we demonstrate that the superbasic cobalt(II) amide Co(TMP)
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