ArticleChemistry, an Asian journal2026
Synthesis, Characterization, and Photobiological Evaluation of Novel Acetyl-Glycosylated Corroles as Potential Photosensitizers.
Article in Chemistry, an Asian journal, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
This work reports the synthesis, structural characterization, and photophysical and electrochemical evaluation of a novel series of mono-(acetyl-glycosylated) free-base corroles. The molecules were prepared using classical Gryko methodologies, yielding four new acetyl-glycosylated derivatives alongside a nonglycosylated reference compound. A complete spectroscopic and analytical characterization was performed, including absorption, steady-state, and time-resolved fluorescence, and electrochemical studies. Detailed analysis of the singlet and triplet excited states, supported by DFT calculations and natural transition orbital (NTO) analysis, confirmed the nature of the electronic transitions and provided insight into excited-state geometries. Furthermore, the derivatives were evaluated for key photobiological properties: all compounds demonstrated efficient singlet oxygen (
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