Perylene Diimide-Derived Bis(Macrocyclic) Ligand Affords Chiral Multinuclear Pd(II) Complexes via Direct Bay-Region Palladation.

He-Ye Zhou, Shasha Yan, Huaxi He, Yuhua Wang, Jiaying Yan, Piotr J Chmielewski, Frank Würthner, Bin Liu

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

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3 · Its place in the literature

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4 · The record

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5 · Who and what money

Authors and funding

8 authors.

He-Ye ZhouCollege of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, Hubei, China.

Shasha YanCollege of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, Hubei, China.

Huaxi HeCollege of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, Hubei, China.

Yuhua WangCollege of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, Hubei, China.

Jiaying YanCollege of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, Hubei, China.

Piotr J ChmielewskiDepartment of Chemistry, University of Wrocław, Wrocław, Poland.

Frank WürthnerInstitut Für Organische Chemie, Universität Würzburg, Würzburg, Germany.

Bin LiuCollege of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang, Hubei, China.

Funding

111 Project of China D20015Hubei Provincial Natural Science Foundation 2024AFB152Hubei Provincial Natural Science Foundation 2024AFB212National Natural Science Foundation of China 22201158National Natural Science Foundation of China 22401173

6 · The paper itself

Abstract

Macrocyclic ligands provide powerful access to structurally defined multi-metallic architectures, yet direct π-core metalation of imide-functionalized polycyclic aromatic dyes remains difficult to control. Herein, we present the design and synthesis of a new nitrogen-rich bis(macrocyclic) ligand (1) based on a perylene diimide (PDI) scaffold. Coordination of Pd(II) to this ligand triggers direct C─H palladation at the bay region of the PDI, yielding two distinct complexes-a bis‑Pd and a tetra‑Pd species (1-Pd

Indexed as

chiralitymacrocyclic ligandsmulti‐metallic complexespalladiumperylene diimide

Identifiers

PMID42287689

DOI10.1002/anie.8176990

PMCPMC13411205

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.