ArticleNature communications2026
Unraveling the mechanistic origins of efficiency and stereoselectivity in EDA-mediated photocatalysis.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
Visible-light-driven electron-donor-acceptor (EDA) photocatalysis holds transformative potential for asymmetric synthesis, yet its efficiency and selectivity are dictated by excited-state dynamics that have, until now, eluded direct observation. Here, we utilize femtosecond and nanosecond transient absorption spectroscopy to investigate a prototypical EDA system: asymmetric α-alkylation of aldehydes. Our real-time kinetic mapping successfully resolves the singlet charge-transfer state (¹CT), triplet charge-transfer state (
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