ArticleJournal of the American Chemical Society2026
Cation-Induced Interphasial Viscosity Variations on Gold Electrocatalysts in Nanoconfined Aqueous Electrolytes.
Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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6 authors.
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Abstract
The structure and viscosity of interfacial hydration layers critically govern charge-transfer, kinetics, and molecular diffusivity in electrocatalysis and energy conversion. Yet, despite their relevance particularly in confined catalysis, the viscosity variations across interfacial zones, of a finite width (interphases), remain largely unexplored. Here, we combine localized friction force analysis and molecular dynamics simulations, to reveal how alkali metal cations influence the hydrogen-bond network of gold-electrolyte interfaces under nanoconfinement. For potassium cations (K
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