PdCu@rGO-based Electrochemical Sensor for Rapid Detection of Catechol.

Catechol, a prevalent phenolic pollutant in food products, poses a significant threat to food safety, necessitating the development of rapid and sensitive detection methods. To overcome the limitations of conventional analytical techniques, such as expensive equipment and operational complexity, electrochemical sensors have gained considerable attention owing to their rapid response and facile miniaturization. However, the rational design of sensing materials that exhibit both high sensitivity and selectivity remains a significant challenge. Herein, a series of PdCu bimetallic nanoparticles supported on reduced graphene oxide (PdCu@rGO) composites with varying Pd/Cu molar ratios was synthesized via a one-step liquid-phase reduction method. Owing to the synergistic electronic effects between Pd and Cu and the high electrical conductivity of the rGO support, the resulting nanocomposites exhibited excellent electrocatalytic activity toward catechol oxidation. At the optimal Pd/Cu molar ratio of 1:2, the fabricated Pd