A Simulation Study of a Novel Electrokinetic-Based Focusing Technique to Enhance the Real-Time Detection of Microplastics in Water Flow.

The contamination of aquatic environments, including treated and drinking water, by microplastics poses a significant threat to ecosystems and human health. Current detection methods often rely on slow laboratory-based tests and offline analysis, which do not support real-time monitoring. This paper presents a novel focusing and concentrating device designed to enhance the real-time detection of microplastics in flowing water. The device utilizes an electrokinetic manipulation mechanism to focus microplastics toward the center of the water flow inside a pipe or fluid channel. A set of 3D rectangular electrodes, with dimensions of 5 mm × 2.5 mm × 1 mm, are arranged circumferentially and longitudinally along the inner perimeter of the fluid channel to generate an intense, non-uniform electric field. Simulation results indicate that microplastics near the channel wall experience a repulsive force on the order of 10-16 to 10-10 N toward the channel center. The applied signal amplitude and the physical properties of the microplastics strongly influence this repulsive force. The trajectories and output concentration of microplastics are investigated under varied conditions. A Voltage of approximately 25 V and a flow rate of 0.05 m/s are found to be ideal for concentrating microplastics into a narrow particle stream, enabling more efficient downstream detection and analysis. Pre-concentrating microplastics in fluid channels prior to sensing is expected to increase sensor sensitivity and improve selectivity.