Evidence map›Paper›PMID 42280506›Full record

ArticlePolymers2026

Orientation-Induced Structure-Property Relationships in Recycled PET-Based Blends Containing Amorphous Copolyesters and Polycarbonate.

Nadiya Sova, Bogdan Savchenko, Aleksander Slieptsov, Viktoriia Plavan, Alina Vozniak, Victor Beloshenko

Abstract read
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Article in Polymers, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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2 · The registry

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3 · Its place in the literature

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4 · The record

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5 · Who and what money

Authors and funding

6 authors.

Nadiya SovaKyiv National University of Technology and Design, Nemirovicha Danchenko Street, 2, 01011 Kyiv, Ukraine.
Bogdan SavchenkoKyiv National University of Technology and Design, Nemirovicha Danchenko Street, 2, 01011 Kyiv, Ukraine.
Aleksander SlieptsovKyiv National University of Technology and Design, Nemirovicha Danchenko Street, 2, 01011 Kyiv, Ukraine.
Viktoriia PlavanKyiv National University of Technology and Design, Nemirovicha Danchenko Street, 2, 01011 Kyiv, Ukraine.ORCID 0000-0001-9559-8962
Alina VozniakCentre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza Street, 112, 90001 Lodz, Poland.
Victor BeloshenkoDonetsk Institute for Physics and Engineering Named After O.O. Galkin, National Academy of Sciences of Ukraine, Pr. Nauki, 46, 03028 Kyiv, Ukraine.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The presence of polymeric impurities in recycled polyethylene terephthalate (PET) streams, particularly amorphous copolyesters such as polyethylene terephthalate glycol-modified (PETG) and polycyclohexylenedimethylene terephthalate glycol-modified (PCTG), as well as polycarbonate (PC), represents a critical challenge for high-performance applications involving orientation drawing. In this study, the influence of such components on the orientation behavior and resulting mechanical properties of PET-based blends was systematically investigated. Model blends were prepared using virgin materials and processed into monofilaments via inline melt spinning followed by controlled orientation drawing with draw ratios up to 6.5. The evolution of tensile strength, modulus, elongation at break, density, and thermal shrinkage was analyzed as a function of draw ratio. The results demonstrate that PET-rich systems exhibit superior mechanical performance, which is consistent with the development of strain-induced crystallization during orientation drawing, reflected in increased density and reduced thermal shrinkage at higher draw ratios. In contrast, amorphous copolyesters (PETG, PCTG) suppress crystallization, resulting in limited structural development, lower modulus, and significantly higher thermal shrinkage. Blends containing polycarbonate showed reduced maximum draw ratios and tensile strength, indicating restricted orientation capability, but exhibited comparatively low shrinkage at moderate draw levels. The study establishes clear structure-property relationships linking molecular orientation, crystallization behavior, and macroscopic performance in PET-based blends. The findings highlight that even minor amounts (~10 wt%) of amorphous polyester impurities can significantly alter orientation efficiency and end-use properties, emphasizing the importance of feedstock control in recycling processes targeting high-performance-oriented products such as strapping tapes and monofilaments.

Indexed as

orientation drawingpolycarbonatepolycyclohexylenedimethylene terephthalate glycol-modifiedpolyethylene terephthalatepolyethylene terephthalate glycol-modifiedpolymer blendsrecycling

Identifiers

PMID42280506
PMCPMC13259493

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.