CPCM/OSS Backfill Materials: Enhanced Thermal Properties and Heat Transfer Performance for Ground Heat Exchangers in Ground Source Heat Pump Systems.

This study focuses on optimizing backfill materials to enhance the heat transfer performance of ground heat exchangers (GHEs) in ground source heat pump (GSHP) systems. A series of composite phase change material/original sand soil (CPCM/OSS) backfill materials was prepared using capric acid-myristic acid/expanded graphite (CA-MA/EG) at mass ratios of 5%, 10%, 15%, and 20%. Thermal conductivity testing, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), laboratory heat transfer tests, and 3D numerical simulations under typical intermittent summer conditions were systematically conducted. The results show that thermal conductivity, specific heat capacity, and thermal storage coefficient all increase with rising moisture content and CPCM dosage. The newly developed CPCM/OSS backfill material significantly improves the heat transfer performance of GHEs. Comprehensive thermophysical characterization indicates that the 10 wt% CPCM sample is the optimal formulation. Laboratory tests demonstrate that, relative to pure OSS backfill, the 10 wt% CPCM-doped CPCM/OSS raises the average soil temperature by approximately 2.5-2.8 °C. Numerical simulations over three consecutive days show that, relative to pure OSS backfill, the 10 wt% CPCM-doped composite enhances the heat exchange capacity per linear meter of the GHEs by 8.8%. The newly developed CPCM/OSS backfill material significantly improves the heat transfer performance of GHEs. It provides a feasible material solution and technical reference for GSHP system design.