ArticleMolecules (Basel, Switzerland)2026
Stable Core-Shell ZIF-8@TPPa Hybrids: Synthesis and Enhanced Herbicide Removal from Water.
Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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10 authors.
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Abstract
The excessive use of herbicides in agricultural fields has emerged as a critical environmental concern. This study innovatively synthesized a ZIF-8@TPPa composite through a solvothermal method for the efficient removal of herbicides from aqueous environment. The material exhibited remarkable adsorption capacities for butachlor (232.56 mg/g), anilofos (188.68 mg/g), and pendimethalin (285.71 mg/g), along with excellent acid-base stability (pH 3-9), strong anti-ion interference capability, and good reusability (adsorption efficiency >80% after five cycles). The adsorption processes were well-described by the two isotherm models and the pseudo-second-order model, indicating that the dominant mechanism is a synergistic effect between monolayer chemical adsorption and multilayer physical adsorption, primarily driven by π-π stacking, hydrogen bonding, and coordination. The material maintained outstanding adsorption efficiency (>85%) in real water samples (tap water, seawater, and river water). This study not only provides a sustainable and effective strategy for herbicide remediation from aqueous environment but also expands the practical applications of MOF@COF in aqueous environment.
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