Controls on natural hydrogen generation during serpentinization of mantle rocks.

Mantle rocks undergoing serpentinization can generate significant amounts of natural hydrogen, yet the rates and controlling processes remain poorly understood. Here, we constrain the possible hydrogen generation rates in two distinct mantle rock types, the fertile lherzolites of the Western Pyrenees and the depleted harzburgites of Northern California, to relatively low rates of ~0.1 to ~0.5 tonnes H₂ yr⁻¹ km⁻³ of reactive rock. When integrated over the full reactive volumes, this corresponds to total production rates of ~300 to ~600 tonnes H₂ yr⁻¹. By combining three-dimensional geophysical inversion with numerical modelling of fluid-rock processes, we show that hydrogen generation rates are mainly limited by H₂ saturation in the fluid and reaction kinetics. Under these constraints, hydrogen generation in mantle-derived serpentinization systems proceeds slowly, making rapid large-scale replenishment unlikely and suggesting that large, economically relevant accumulations, would require timescales of thousands to tens of thousands of years to develop.