ArticleNature communications2026
Flexural phonon instability defines intrinsic van der Waals elastic limits in the interlayer direction.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Frenkel's cohesive model predicts an ideal elastic strain limit of ~10% for strong solids, a bound upheld in conventional materials. We demonstrate that such consistency breaks down in van der Waals (vdW) solids, challenging established strength theories. In situ tensile tests, combined with first-principles calculations, reveal unexpected localized decohesion failure at only ~3% strain in graphite and ~2% in h-BN along the interlayer direction-well below defect-controlled limits-defining their intrinsic elastic limits. This localization phenomenon is absent in MoS
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