ArticleGeobiology
Contrasting Rare Earth Element Signatures Between Stromatolitic Carbonates and Lagoon Waters at Shark Bay, Western Australia: Implications for Paleo-Environmental Reconstructions of Microbial Habitats.
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Abstract
Rare earth elements and yttrium (REY) signatures in stromatolitic carbonates have emerged as powerful geochemical proxies for reconstructing paleo-depositional environments of microbial habitats. The applicability of such a proxy relies on the assumption that REY substitutes for calcium into crystal lattices, directly reflecting the composition of the fluid from which the carbonate precipitated. The REY signatures of stromatolites are often similar to those of open ocean seawater. In restricted environments, however, REY fractionation can occur between waters and stromatolites, questioning their reliability to reconstruct microbial habitats through Earth's history. In this contribution, we determined the REY concentrations and partition coefficients (Kd
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