ArticleAngewandte Chemie (International ed. in English)2026
Conformationally Adaptive Crown Ether Embedded in a Metal Sulfide for Exceptional Strontium Capture.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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13 authors.
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Abstract
Precise conformational control of flexible supramolecular moieties (e.g., crown ethers) in crystalline-state adsorbents is essential for efficient host-guest recognition. Traditional strategies relying on covalent chemistry are often limited by either tedious synthesis or a sacrifice of conformational flexibility. Here, we introduce a simple non-covalent anchoring strategy where 18-crown-6 (18Cr6) molecules are in-situ embedded between the interlayer galleries of a perforated thiostannate framework (18Cr6-SnS) in one-pot synthesis. This architecture not only ensures ordered alignment of crown ethers but also preserves the intrinsic coordination freedom, thereby enabling exceptional Sr
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