ArticlePolymer science & technology (Washington, D.C.)2025
Deep Eutectic Solvent-Mediated Engineering of Polyamide Membranes for High-Performance Loose Nanofiltration.
Article in Polymer science & technology (Washington, D.C.), 2025. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
With growing demands for the efficient separation and recovery of high-value components, loose nanofiltration (LNF) has emerged as a promising membrane technology. However, the development of LNF membranes presents ongoing challenges in achieving precise structural control through conventional water/alkane interfacial polymerization. Herein, we developed an innovative anhydrous interfacial polymerization strategy for fabricating high-performance polyamide membranes that can be tailored for LNF applications. This approach employs a deep eutectic solvent (DES) as the amine monomer solvent, interface regulator, and polymerization mediator. In contrast to water/alkane interfacial systems, the polymerization between piperazine and trimesoyl chloride at the DES/cyclohexane interface facilitates the formation of an ultrathin loose polyamide layer with precisely controlled pore architecture. The resultant membrane exhibits a high water permeance of 48 L m
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