ArticleElectrophoresis2026
Electrophoresis of Charged Dielectric Droplet With Ion Concentration Polarization Effect.
Article in Electrophoresis, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Droplet electrophoresis is one of the most commonly used methods for measuring the charge at two-liquid interfaces. However, there is still a lack of analytical solutions that consider the ion concentration polarization mechanism with asymmetric ion distribution under high surface charge. Based on the thin electric double layer assumption, we construct the asymptotic form of the macroscopic model of dielectric droplet electrophoresis and establish the coarse-grained effective interface condition across the diffuse layer regions through the heuristic treatment extending the method of matched asymptotic expansion, revealing the coupling mechanism between ion concentration polarization and permittivity-induced inhomogeneous charging. An analytical solution under the weak-external-field limit is provided, demonstrating a nonmonotonic dependence of electrophoretic mobility on the
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