Evidence map›Paper›PMID 42252695›Full record

ArticleJournal of the American Chemical Society2026

Programmable Functionalizations of Tetramethylpiperidine N-Oxyl (TEMPO)-Acrolein Linchpins Derived from Alkoxyallenes.

Ken S Lee, Colin S Crawford, George T Cheng, Jensen J Zerban, Emanuele Casali, Subir Panja, Daniel S Rampon, Jennifer M Schomaker

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Ken S LeeDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706, United States.ORCID 0000-0001-6785-6805
Colin S CrawfordDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706, United States.ORCID 0009-0000-4786-6520
George T ChengDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706, United States.
Jensen J ZerbanDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706, United States.
Emanuele CasaliDepartment of Chemistry, University of Pavia, Viale Taramelli 12, 27100 Pavia, PV, Italy.ORCID 0000-0001-7501-5213
Subir PanjaDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706, United States.ORCID 0000-0002-8682-6094
Daniel S RamponDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706, United States.ORCID 0000-0003-0712-6645
Jennifer M SchomakerDepartment of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, Wisconsin 53706, United States.ORCID 0000-0003-1329-950X

Funding

Harnessing divergent reactivities of unusual reactive intermediates as platforms to explore high Fsp3 amine chemical spaceR35GM152043 · NIGMS · UNIVERSITY OF WISCONSIN-MADISON · PI Jennifer Marie Schomaker · 2024 to 2026
$1.3M
NIGMS NIH HHS R35 GM152043
6 · The paper itself

Abstract

Allenes are versatile precursors for constructing complex molecular frameworks, yet oxidative transformations to install C-C or C-heteroatom bonds across the C1-C3 framework rely on inconvenient reagents and yield overoxidized byproducts and unstable intermediates that limit downstream diversification. Herein, we report a general strategy to access multifunctional C(sp

Identifiers

PMID42252695
PMCPMC13281524

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.