ArticleAngewandte Chemie (International ed. in English)2026
Interface Passivation Inhibition Enabled by Anode-Cathode Synergistic Engineering for High-Efficiency Electrodeposition of Transition Metals.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Room-temperature electrodeposition is widely used to fabricate transition-metal materials and alloys, but severe interfacial passivation drastically reduces current efficiency. More importantly, the intrinsic origin of interfacial passivation remains insufficiently understood, which has hampered the development of effective mitigation strategies. Herein, taking multivalent Ti as a representative example, we demonstrated that the bonding between Ti-Cl and the electrode downshifts the d-band center of the electrode by 0.15 eV, markedly suppressing ion adsorption and charge transfer at the interface. Further operando studies showed that anodic dissolution generated [Ti(Al
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