Outer-Sphere Tuning of Synthetic Iron-Sulfur Clusters Within Nanoscale Cage Frameworks.

Rupal Baliyan, Shelby T Davis, Jan-Niklas Boyn, Gwendolyn A Bailey

Abstract read

In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Rupal BaliyanDepartment of Chemistry, University of Minnesota, Twin Cities, Minnesota, USA.

Shelby T DavisDepartment of Chemistry, University of Minnesota, Twin Cities, Minnesota, USA.

Jan-Niklas BoynDepartment of Chemistry, University of Minnesota, Twin Cities, Minnesota, USA.

Gwendolyn A BaileyDepartment of Chemistry, University of Minnesota, Twin Cities, Minnesota, USA.ORCID https://orcid.org/0000-0002-6636-4128

Funding

Upgrade of a 500 MHz NMR Spectrometer for Applications in Biomedical ResearchS10OD011952 · OD · UNIVERSITY OF MINNESOTA · PI HOYE, THOMAS R. · 2012 to 2012

$378k

National Institute of Health Office of the Director Award #S10OD011952National Science Foundation, Earth Sciences Division NSF EAR-2153786NIH HHS S10 OD011952NNCI ECCS-2025124NSF through the MRSEC DMR-2011401

6 · The paper itself

Abstract

As atomic-scale archetypes for multi-electron transfer, iron-sulfur clusters are compelling candidates for the design of redox-active, catalytic nanomaterials; yet, translating their enzymatic proficiency into robust synthetic platforms remains a challenge. A key bottleneck lies in replicating the outer-sphere environment, which modulates the cluster's electronic landscape, provides site-isolation, and facilitates catalytic pathways via programmable noncovalent interactions. Herein, we demonstrate a host-guest strategy for systematically tuning iron-sulfur cofactor models within tetrahedral [M

Indexed as

bioinspired chemistryhost‐guest chemistryhydrophobic effectsiron–sulfur clustersmetallocofactorsouter coordination sphereX‐ray photoelectron spectroscopy

Identifiers

PMID42246287

DOI10.1002/smll.74001

PMCPMC13533253

What OpenQuestion holds

Textmetadata

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.