Evidence map›Paper›PMID 42240480›Full record

ArticleSmall (Weinheim an der Bergstrasse, Germany)2026

Molecular Engineering of Fluorinated Nitriles as Self-Passivating Electrolyte for High Voltage Lithium Metal Batteries.

Yunpeng Fu, Yang Wang, Wanglei Chen, Wenjing Ni, Junjie Lu, Shaojun Qiu, Yiru Wang, Zuxian Cai, Zilong Tang, Zhaoxu Wang and 1 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Yunpeng FuSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Yang WangSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Wanglei ChenSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Wenjing NiSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Junjie LuSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Shaojun QiuSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Yiru WangSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Zuxian CaiSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Zilong TangSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Zhaoxu WangSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.
Jinglun WangSchool of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan, P. R. China.ORCID https://orcid.org/0000-0002-3569-7202

Funding

National Natural Science Foundation of China 22472051Natural Science Foundation of Hunan Province of China 2024JJ71Yuelushan Center for Industrial Innovation 2023YCII0108
6 · The paper itself

Abstract

Electrolyte engineering is essential for developing high-voltage lithium metal batteries (HV-LMBs). Nitrile-based compounds are one of the most promising electrolyte solvents with high chemical and oxidative stability, but their low stability against lithium metal anode is a notorious problem that hinders its practical applications. Herein, through molecular engineering of modulating the fluorination degree, partially fluorinated nitrile compounds were first reported, enabling self-passivation toward lithium metal anodes. Both theoretical calculation and experimental results revealed that the mono-fluorinated nitrile (F1EON) based solvent not only exhibits a horizontal adsorption configuration on the lithium metal surface, resulting in the spontaneous formation of a dense LiF passivation layer, but also forms a unique tridentate solvation structure, thereby inducing a LiF-rich cathode electrolyte interphase. Consequently, the 4.6 V high-voltage Li||LiCoO

Indexed as

fluorinated nitrileslithium metal batteriesmolecular engineeringself‐passivation

Identifiers

PMID42240480
PMCPMC13392733

What OpenQuestion holds

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.