ArticleAngewandte Chemie (International ed. in English)2026
Ordered Ionic-Liquid Channels Enable Fast Anhydrous Proton Conduction at up to 240°C for Fuel Cells.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Intermediate-temperature electrochemical technologies offer a range of important advantages but require high-performance and robust anhydrous proton exchange membranes. Herein, we demonstrate that confinement of phosphonium-, imidazolium-, and sulphonium-based ionic liquids (ILs), within channels formed by stacked monolayers of boron nitride and graphene nanosheets functionalised with polyethyleneimine, provides robust and effective proton conductivity while suppressing bulk diffusion of the IL ions. We propose that the positively charged nanosheets might induce spatial ionic ordering, anchoring anions near the channel walls while concentrating protons and cations along the central region to establish parallel, continuous pathways for rapid proton transfer under anhydrous conditions. The resulting solid-state composite membranes exhibit stable anhydrous proton conductivities of up to 10
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