A Doubly Twisted Molecular Nanocarbon With Substantial π-Overlap: Facile Synthesis, Chiral Resolution, and Through-Space Electronic Coupling.

Jiawei Shao, CiHui Lin, Yuguang Sui, Meng Wang, Wei Fan, Yong Ni

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

6 authors.

Jiawei ShaoDepartment of Chemistry, State Key Laboratory of Quantum Functional Materials, Southern University of Science and Technology, Shenzhen, China.

CiHui LinDepartment of Chemistry, State Key Laboratory of Quantum Functional Materials, Southern University of Science and Technology, Shenzhen, China.

Yuguang SuiDepartment of Chemistry, State Key Laboratory of Quantum Functional Materials, Southern University of Science and Technology, Shenzhen, China.

Meng WangDepartment of Chemistry, State Key Laboratory of Quantum Functional Materials, Southern University of Science and Technology, Shenzhen, China.

Wei FanSchool of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, China.

Yong NiDepartment of Chemistry, State Key Laboratory of Quantum Functional Materials, Southern University of Science and Technology, Shenzhen, China.ORCID https://orcid.org/0000-0002-3844-0103

Funding

Excellent Young Scientists Fund Program K23211106Guangdong Innovative and Entrepreneurial Research Team Program 2023ZT10Y058Guangdong Provincial Key Laboratory of Sustainable Biomimetic Materials and Green Energy 2024B121201003Innovation Commission of Shenzhen Municipality 20231116124346001National Natural Science Foundation of China 22375085State Key Laboratory of Quantum Functional Materials K251490701

6 · The paper itself

Abstract

Twisted molecular nanocarbons (TMNCs) represent attractive targets due to their persistent chirality and potential through-space electronic interactions, which remain largely unrevealed. Herein we report an efficient synthesis of a figure-eight TMNC 1 with substantial π-overlap, by using a quantitative, four-fold regioselective Scholl reaction. The (P,P)- and (M,M)- enantiomers can be readily separated by preparative TLC plate, enabling persistent chiroptical properties with moderate dissymmetric factors (|g

Indexed as

regio‐selective Scholl reactionspatial aromaticityspin polarizationthrough‐space electronic couplingtwisted molecular nanocarbon

Identifiers

PMID42231700

DOI10.1002/anie.5579143

PMCPMC13427213

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