ArticleAdvanced materials (Deerfield Beach, Fla.)2026
2D Perovskite Engineering Enables Robust Self-Assembled Monolayers for High-Performance Perovskite Solar Cells.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Self-assembled monolayers (SAMs) are critical hole-selective contacts in inverted perovskite solar cells (PSCs), yet their practical implementation is hindered by desorption and aggregation during solution-based perovskite deposition. Here, we report a transient two-dimensional (2D) perovskite protection strategy using volatile propylammonium chloride, which temporarily shields SAMs from solvent-induced degradation and subsequently decouples during thermal annealing. This mechanism preserves the integrity of the SAM interface while enabling uniform crystallization of large-area perovskite films and efficient charge extraction. Consequently, PSCs achieve a power conversion efficiency (PCE) of 26.14% for 0.05 cm
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