ArticleAdvanced materials (Deerfield Beach, Fla.)2026
Energetic All-Polymer Fiber Batteries Enabled by Interface-Interlocked Water-In-Network Electrolytes for Wearable Electronics.
Article in Advanced materials (Deerfield Beach, Fla.), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
All-polymer batteries configured in a fibrous form by integrating polymeric electrodes with aqueous quasi-solid polymer electrolytes (AQPEs) represent a promising solution for wearable electronics with safety and sustainability. However, their practical development is constrained by the narrow electrochemical stability window (ESW) of AQPEs and the structural instability of electrode-electrolyte interfaces under deformation. Here, we present a "water-in-network" (WIN) electrolyte that precisely engineers water activity and dynamics by modulating the crosslinking density of the polymer network. We unanticipatedly discover a distinct "water confinement" effect wherein water activity exhibits a non-monotonic dependence on crosslinking density, originating from the structural evolution of the network. Benefiting from this mechanism, the ESW significantly expands to 3.4 V, endowing an all-polymer sodium-ion fiber battery with an energy density of 92.4 Wh kg
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