ArticleACS omega2026
Mixed Matrix Membrane for Cr(VI) Adsorption and Reduction: Joining Click Chemistry and MOFs.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
5 authors.
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Abstract
In this work, a maleimide-bearing biobased polyurethane is made to react with a metal-organic framework (MOF) containing thiol pendant groups (Zr-MSA), to produce a functional mixed matrix membrane (MMM). The membrane is synthesized following an innovative method in which Zr-MSA acts as a cross-linker through UV-promoted thiol-Michael addition while providing the ability to trap Cr-(VI) and reduce it to Cr-(III). By means of a comprehensive study of the surface morphology and adsorption kinetics, the adsorption mechanism is elucidated. The homogeneous distribution of the MOF allows for a high cross-linking degree and adsorption ability, resulting in an MMM with good mechanical properties and filtering capacity. Using the thiol-maleimide click reaction, this new strategy permits easy incorporation of MOFs into a membrane without affecting their functionality, leveraging them as active cross-linkers.
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Registered trials
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