ArticleMacromolecules2026
Carboxyl Dissociation Degree (
Article in Macromolecules, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Understanding the dissociation process in weakly charged polymer membranes is essential to design innovative charged polymer membranes with desirable transport properties for broader applications in sustainability. Previously, we designed a library of weakly charged polymer membranes, i.e., cross-linked acrylic acid (AA)-poly-(ethylene glycol) diacrylate (PEGDA) (AA-PEGDA) random copolymer networks with a wide ion-exchange capacity (IEC = 0-4 mequiv/g) range and limited water swelling. Here, we report the dissociation process of the weakly charged AA-PEGDA series in dilute (DI water) and concentrated (1 M NaCl (aq)) external salt solutions by probing dissociation in both 1) a solution phase (via potentiometric (POT) titration) and 2) a polymer phase (via ATR-FTIR analysis). Both POT titration and ATR-FTIR analysis describe the dissociation process well, showing similar dissociation parameters (degree of ionization (
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