Chirality Transfer in Gold Nanoclusters: Insights from Chiral Spectroscopy and Theoretical Modeling.

Rareş Banu, Chiara Morassut, Ariel Perez Mellor, Thomas Bürgi, Mauro Stener, Noelia Barrabés

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Article in ACS physical chemistry Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

6 authors.

Rareş BanuInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.

Chiara MorassutDepartment of Chemical and Pharmaceutical Sciences, University of Trieste, Via Giorgieri 1, 34127 Trieste, Italy.

Ariel Perez MellorDepartment of Physical Chemistry, University of Geneva, 30 Quai Ernest Ansermet, CH-1211 Genéve 4, Switzerland.ORCID https://orcid.org/0000-0002-3134-328X

Thomas BürgiDepartment of Physical Chemistry, University of Geneva, 30 Quai Ernest Ansermet, CH-1211 Genéve 4, Switzerland.ORCID https://orcid.org/0000-0003-0906-082X

Mauro StenerDepartment of Chemical and Pharmaceutical Sciences, University of Trieste, Via Giorgieri 1, 34127 Trieste, Italy.ORCID https://orcid.org/0000-0003-3700-7903

Noelia BarrabésInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.ORCID https://orcid.org/0000-0002-6018-3115

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Chirality in atomically precise gold nanoclusters emerges from the interplay among the metal core, the metal-ligand interface, and the ligand shell, yet how these hierarchical elements influence ligand conformation remains unclear. This work investigates chirality transfer from the nanocluster framework to the ligand sphere by using vibrational circular dichroism (VCD) spectroscopy combined with density functional theory and SCC-DFTB calculations. Three enantiopure thiolate-protected gold nanoclustersAu

Indexed as

chiralitydensity functional calculationsgold nanoclustersspectroscopyvibrational circular dichroism

Identifiers

PMID42221936

DOI10.1021/acsphyschemau.6c00014

PMCPMC13220208

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