Evidence map›Paper›PMID 42218772›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Enzyme-Like Synthetic Cleft for Light-Driven Water-Oxidation Catalysis Via an Oxide Relay Pathway.

Daniel A P Friedewald, Gourab Das, Philipp H Kirchner, Olga Anhalt, Deqi Tang, Sandra Luber, Florian Beuerle, Frank Würthner

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Daniel A P FriedewaldInstitut für Organische Chemie, Universität Würzburg, Würzburg, Germany.
Gourab DasInstitut für Organische Chemie, Universität Würzburg, Würzburg, Germany.
Philipp H KirchnerInstitut für Organische Chemie, Universität Würzburg, Würzburg, Germany.
Olga AnhaltCenter for Nanosystems Chemistry (CNC), Universität Würzburg, Würzburg, Germany.
Deqi TangDepartment of Chemistry, University of Zürich, Zürich, Switzerland.
Sandra LuberDepartment of Chemistry, University of Zürich, Zürich, Switzerland.ORCID https://orcid.org/0000-0002-6203-9379
Florian BeuerleInstitut für Organische Chemie, Universität Tübingen, Tübingen, Germany.ORCID https://orcid.org/0000-0001-7239-8327
Frank WürthnerInstitut für Organische Chemie, Universität Würzburg, Würzburg, Germany.ORCID https://orcid.org/0000-0001-7245-0471

Funding

Bavarian State Ministry for Science and the Arts within the Solar Technology Go Hybrid programEuropean Union's Horizon 2020 research and innovation program 787937
6 · The paper itself

Abstract

Harnessing functional groups in the outer coordination sphere to direct catalytic pathways is characteristic for enzymes, yet rather underexplored for man-made catalysts. Here, following our earlier work on Ru(bda) water oxidation catalysts (bda = 2,2'-bipyridine-6,6'-dicarboxylate), we demonstrate how a carboxyl-functionalized Ru(bda)-based macrocycle enables an oxide relay mechanism in light-driven water oxidation via an O─O bond formation between carboxylate and Ru

Indexed as

artificial photosynthesishomogeneous catalysisphotocatalysisruthenium complexeswater oxidation

Identifiers

PMID42218772
PMCPMC13360865

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.