Evidence map›Paper›PMID 42216812›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Two-Dimensional Metal-Organic Frameworks as Charge Extraction Media Enabling Binary Organic Solar Cells With 20.70% Efficiency.

Ziwei Zhang, Xiaopeng Duan, Junjie Zhang, Jiawei Deng, Busheng Zhang, Mingxu Zhou, Yun Li, Guangkuo Dai, Xunchang Wang, Renqiang Yang and 4 more

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
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1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Ziwei ZhangState Key Laboratory of Bioinspired Interfacial Materials Science, International Research Center For Carbon Neutralization, Hangzhou International Innovation Institute, Beihang University, Hangzhou, People's Republic of China.
Xiaopeng DuanState Key Laboratory of Bioinspired Interfacial Materials Science, International Research Center For Carbon Neutralization, Hangzhou International Innovation Institute, Beihang University, Hangzhou, People's Republic of China.
Junjie ZhangSchool of Chemistry, Beihang University, Beijing, People's Republic of China.
Jiawei DengSchool of Chemistry, Beihang University, Beijing, People's Republic of China.
Busheng ZhangInstitute of Functional Nano & Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, State Key Laboratory of Bioinspired interfacial Materials Science, Soochow University, Suzhou, People's Republic of China.
Mingxu ZhouSchool of Physics State Key Laboratory of Crystal Materials, Shandong University, Jinan, People's Republic of China.
Yun LiSchool of Chemistry, Beihang University, Beijing, People's Republic of China.
Guangkuo DaiSchool of Chemistry, Beihang University, Beijing, People's Republic of China.
Xunchang WangKey Laboratory of Flexible Optoelectronic Materials and Technology (Ministry of Education), School of Optoelectronic Materials & Technology, Jianghan University, Wuhan, People's Republic of China.
Renqiang YangKey Laboratory of Flexible Optoelectronic Materials and Technology (Ministry of Education), School of Optoelectronic Materials & Technology, Jianghan University, Wuhan, People's Republic of China.ORCID https://orcid.org/0009-0000-7554-262X
Xiaotao HaoSchool of Physics State Key Laboratory of Crystal Materials, Shandong University, Jinan, People's Republic of China.ORCID https://orcid.org/0000-0002-0197-6545
Xiankai ChenInstitute of Functional Nano & Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, State Key Laboratory of Bioinspired interfacial Materials Science, Soochow University, Suzhou, People's Republic of China.ORCID https://orcid.org/0000-0002-8580-7246
Xiaobo SunState Key Laboratory of Bioinspired Interfacial Materials Science, International Research Center For Carbon Neutralization, Hangzhou International Innovation Institute, Beihang University, Hangzhou, People's Republic of China.ORCID https://orcid.org/0000-0003-2674-2662
Yanming SunState Key Laboratory of Bioinspired Interfacial Materials Science, International Research Center For Carbon Neutralization, Hangzhou International Innovation Institute, Beihang University, Hangzhou, People's Republic of China.ORCID https://orcid.org/0000-0001-7839-3199

Funding

Beijing Natural Science Foundation Z230018National Natural Science Foundation of China 22575009National Natural Science Foundation of China 52503225National Natural Science Foundation of China W2511056 52333005Postdoctoral Research Funding of Hangzhou International Innovation Institute of Beihang University 2025BKZ017
6 · The paper itself

Abstract

Metal-organic frameworks (MOFs), recognized for their tunable, highly conjugated frameworks and exceptional charge-transport properties, exhibit significant potential in organic solar cells (OSCs). However, their integration has been hampered by inadequate dispersibility in low-polarity solvents. Herein, the two-dimensional MOF materials, Cu-TCPP and Zn-TCPP, were synthesized and precisely infiltrated into the upper region of the active layer through an anti-solvent strategy, which significantly enhanced charge transport through continuous π-d conjugation within the MOF layers. Moreover, intermolecular interactions between MOFs and acceptor L8-BO, including metal-center coordination and π-π effect enabled by conjugated porphyrin ligands, facilitate superior molecular packing, a double-fibril structure, and favorable vertical phase separation. Consequently, Zn-TCPP-incorporated D18:L8-BO OSCs achieve an outstanding efficiency of 20.70%, ranking among the highest reported values for binary devices. Meanwhile, the anchoring effect of MOFs significantly enhances the morphological stability of the active layer, endowing the OSCs with over twofold improvement in operational stability. This work not only opens a novel pathway for integrating high-performance MOF materials into OSCs but also establishes a promising paradigm for constructing efficient charge transport channels and fabricating highly stable, high-performance organic photovoltaics.

Indexed as

anti‐solvent strategyelectron transportintermolecular interactionmetal‐organic frameworksorganic solar cells

Identifiers

PMID42216812
PMCPMC13411573

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.