ArticleInorganic chemistry2026
Ligand Topology Tunes Energy and Character of Emissive Triplet States in Stannylenes.
Article in Inorganic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In the last decades, phosphorescent or photoactive complexes with earth-abundant transition metals have gained huge attention. On the contrary, heavy main group elements with similar properties are rare, in particular group 14 complexes in the oxidation state + II, e.g. tetrylenes. The excited state properties have remained mostly undiscussed and general design concepts for excited state properties─as established for transition metal complexes─are lacking. The present study offers a conceptional topological approach for understanding and addressing specific excited state properties of main group complexes, exemplary discussed by the Sn(
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