ArticleACS macro letters2026
Shaping the Gradient: Ether-Type Polar Modifiers for the Statistical Anionic Copolymerization of Styrene and Isoprene.
Article in ACS macro letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Living anionic copolymerization of isoprene and styrene, initiated by alkyllithium compounds in nonpolar solvent, typically yields commercially relevant tapered copolymers, widely used as thermoplastic elastomers. Lewis base modifiers enable both gradient and microstructure control. Ether-type ligands with varying coordination number were systematically investigated in styrene/isoprene copolymerization in cyclohexane using
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