ArticleAngewandte Chemie (International ed. in English)2026
Tuning Reaction Pathways via Symmetric Fluorination Enables High-Temperature and High-Voltage Electrolytes.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Ni-rich layered oxide cathodes deliver high capacity, but they suffer from severe interfacial instability and thermal safety risks when operated at high voltages and elevated temperatures. Here we propose an electrolyte design strategy based on molecular fluorination symmetry. This approach employs difluoro-symmetric substitution to precisely steer decomposition pathways towards preferential ring-opening reactions, thereby effectively suppressing defluorination decomposition and the concomitant formation of acidic byproducts at elevated temperatures. Through rational molecular engineering of synergistic fluorination, we achieve directed interfacial chemistry control. Under harsh operational conditions (4.5 V, 45°C), the modified cells retain 83% of their capacity after 300 cycles, along with significantly reduced gas generation and an elevated thermal runaway onset temperature. Furthermore, 2 Ah graphite||LiNi
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