ReviewACS earth & space chemistry2026
Interstellar Stereoisomerism.
Review in ACS earth & space chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The increasing detection of new molecules in the interstellar medium (ISM) shows that stereoisomerism is a fundamental contributor to interstellar molecular complexity. This work presents the first comprehensive overview of interstellar stereoisomerism. A total of 16 stereoisomeric pairs have been identified (13 conformational and 3 geometric), spanning molecules with 5-12 atoms and energy separations from ∼10 K to 2667 K. They were observed across diverse astrophysical environments with kinetic temperatures ranging from low to high values (∼7.5 to 300 K). The observed stereoisomeric ratios (OSR)defined as the column density ratio of the higher-energy isomer divided by that of the lower-energy isomervary widely (0.009-4). While systems with small energy differences (<600 K; i.e., ∼1.2 kcal mol
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