ArticleChemistry (Weinheim an der Bergstrasse, Germany)2026
Changing N^C^O to C^N^O Coordination in Cyclometalated Pt(II) and Pd(II) Complexes Modulates Stability and Emission Characteristics: Toward Brighter Versatility.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In this work, we present a new class of cyclometalated Pt(II) complexes bearing tridentate luminophoric chelators. Inspired by picolinato units usually acting as ancillary ligands for phosphorescent Pt(II) and Ir(III) complexes with high-lying triplet states, we herein incorporate this coordination pattern into chelating luminophores toward tridentate pincer ligands (C^N^O) and compared them with a benzoate-derived motif (N^C^O). Both frameworks exhibit excellent photoluminescence efficiencies with quantum yields (Φ
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