ArticleNature communications2026
Atomic-scale revelation of in situ reverse regulation from particles to clusters in the Ni/La-CeO
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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10 authors.
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Abstract
Subnanometer metal cluster catalysts have garnered significant attention due to their multi-site synergistic catalytic capabilities. However, constrained by classical sintering theory, metal clusters are prone to sintering and growth, which makes it challenging for them to stably exist at high temperatures. Prevailing strategies predominantly focus on the synthesis pathways from atoms to clusters, while overlooking the bidirectional regulation potential of metal particle dynamic reconstruction. This study transcends conventional paradigms by proposing a reverse regulation strategy from particles to clusters. The disadvantage of high temperature is strategically converted into driving forces for particle dispersion through the rational design of catalytic environments and metal-support interactions. Through a comprehensive combination of in situ characterization techniques and theoretical calculations, the interfacial atomic migration pathways and energy evolution during dynamic dispersion are systematically investigated. Furthermore, the formation process and underlying mechanism of stable Ni clusters are elucidated. The optimized 10Ni/30La-CeO
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