Evidence map›Paper›PMID 42201175›Full record

ArticleAngewandte Chemie (International ed. in English)2026

Linker-Enabled Self-Nitridation and Multistep Pyrolysis Pathways of Cu-Triazolate MOFs Toward Cu

Chi Song, Junzhen Wei, Guangxue Feng, Zhehao Sun, Yinuo Wang, Xuan Yang, Jiayi Wang, Yanghe Wang, Zongyou Yin, Changjian Li and 2 more

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In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

What it found

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2 · The registry

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

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0 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

12 authors.

Chi SongSchool of Materials and Energy, Guangdong University of Technology, Guangzhou, Guangdong, China.
Junzhen WeiSchool of Materials and Energy, Guangdong University of Technology, Guangzhou, Guangdong, China.
Guangxue FengState Key Laboratory of Luminescent Materials and Devices, School of Materials Science and Engineering, AIE Institute, South China University of Technology, Guangzhou, Guangdong, China.ORCID https://orcid.org/0000-0003-4344-3517
Zhehao SunResearch School of Chemistry, Australian National University, Canberra, Australia.
Yinuo WangDepartment of Chemical and Biological Engineering, Hong Kong University of Science and Technology, Hong Kong, China.
Xuan YangNational University of Singapore (Suzhou) Research Institute, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Jiayi WangDepartment of Chemical and Biological Engineering, Hong Kong University of Science and Technology, Hong Kong, China.
Yanghe WangDepartment of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong, China.
Zongyou YinResearch School of Chemistry, Australian National University, Canberra, Australia.ORCID https://orcid.org/0000-0002-0800-4490
Changjian LiDepartment of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen, Guangdong, China.ORCID https://orcid.org/0000-0002-5779-7466
Anthony K CheethamMaterials Research Laboratory, University of California, Santa Barbara, California, USA.
Yating HuSchool of Materials and Energy, Guangdong University of Technology, Guangzhou, Guangdong, China.

Funding

Guangzhou Municipal Science and Technology Bureau, China SL2024A04J00992National Natural Science Foundation of China 22205067
6 · The paper itself

Abstract

Metal-organic framework (MOF) pyrolysis is widely used to produce functional nanomaterials, yet it is still commonly regarded as a simple thermal decomposition or templating process. Here, we show that a Cu(II)-1,2,3-triazolate (trz) MOF functions as a nanoreactor in which intrinsic metal-linker chemistry governs the evolution of both phase and morphology. Strikingly, the triazole ring remains preserved throughout the pre-pyrolysis phase transitions that lead to the formation of Cu atomic clusters. These highly reactive Cu clusters and the preserved triazolate are essential for the subsequent formation of metal nitride, as they enable efficient nitridation at an unusually low temperature. Without introducing any external nitrogen source, the Cu clusters react with NH

Indexed as

nanomaterialsnanoreactorphase transitionpyrolysisthermal decomposition

Identifiers

PMID42201175
PMCPMC13383247

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.