Evidence map›Paper›PMID 42197324›Full record

ArticleMolecules (Basel, Switzerland)2026

Fe-Exchanged Natural Bentonites from Kazakhstan as Multifunctional Solids for Decontamination from Hazardous Chemicals: Structure-Reactivity Relationships Under Mild Conditions.

Stefano Econdi, Sholpan Nazarkulova, Stefano Marchesi, Chiara Bisio, Mukhambetkali Burkitbayev, Matteo Guidotti

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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2 · The registry

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3 · Its place in the literature

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0 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

6 authors.

Stefano EcondiCNR-SCITEC, Institute of Chemical Sciences and Technologies "Giulio Natta", Via C. Golgi 19, 20133 Milan, Italy.ORCID 0000-0002-3609-1659
Sholpan NazarkulovaCNR-SCITEC, Institute of Chemical Sciences and Technologies "Giulio Natta", Via C. Golgi 19, 20133 Milan, Italy.
Stefano MarchesiDepartment of Sciences and Technological Innovation, University of Eastern Piedmont "A. Avogadro", Viale T. Michel 11, 15121 Alessandria, Italy.ORCID 0000-0003-4183-926X
Chiara BisioCNR-SCITEC, Institute of Chemical Sciences and Technologies "Giulio Natta", Via C. Golgi 19, 20133 Milan, Italy.ORCID 0000-0002-7591-5104
Mukhambetkali BurkitbayevFaculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Av., Almaty 050040, Kazakhstan.ORCID 0000-0002-1472-1293
Matteo GuidottiCNR-SCITEC, Institute of Chemical Sciences and Technologies "Giulio Natta", Via C. Golgi 19, 20133 Milan, Italy.ORCID 0000-0002-9759-2561

Funding

JSC "Center for International Programs" Bolashaq International Scholarship 2025National Research Council FOE "FutuRaw" Project
6 · The paper itself

Abstract

Iron-exchanged bentonites derived from a natural montmorillonite-rich clay (Taganskoe deposit, Kazakhstan) were prepared through a simple aqueous ion-exchange route using Fe(II) or Fe(III) inorganic salt precursors, yielding final Fe contents of ca. 5-7 wt.%, while preserving the smectite layered framework. A mild thermal treatment under air was applied to tune iron coordination without triggering major structural collapse. The resulting materials were characterized by ED-XRF, PXRD, FE-SEM/EDX, DLS/ζ-potential and DR UV-Vis-NIR spectroscopy, revealing predominantly exchanged Fe species with a limited fraction of surface iron-oxide clusters, whose contribution increases after activation. Structure-reactivity relationships were probed under mild conditions in liquid-phase ethyl acetate using dimethyl methylphosphonate (DMMP) and 2-chloroethyl ethyl sulfide (2-CEES) as organophosphorus and organosulfur hazardous chemicals and chemical warfare agent simulants, respectively. Fe(III)-bentonite enabled very fast DMMP removal (ca. 93% within 0.5 h) with a remarkable improved performance with respect to Fe(II)-bentonite and the pristine mineral clay. For 2-CEES, the presence of H

Indexed as

claysdecontaminationheterogeneous oxidationion exchangeironmontmorilloniteorganophosphorus chemicalsorganosulfur compounds

Identifiers

PMID42197324
PMCPMC13210050

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