ArticleMolecules (Basel, Switzerland)2026
Supramolecular Engineering of a Homo[2]catenane Filler Enables Polymer Composites with Exceptional High-Temperature Capacitive Energy Storage.
Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Bipyridine-functionalized Covalent Organic Framework as a Reusable Adsorbent for Trace BTEX Detection in Water Samples.Journal of separation science · 2026Article
- From Biomass Waste to Multifunctional Biochar: Tailored Preparation and Emerging Applications in Energy, Environment, and Sensing.Molecules (Basel, Switzerland) · 2026Review
- An error measurement method for electricity meters based on dynamic test signal modeling with random measurements.Scientific reports · 2026Article
- Review of the Applications of Density Functional Theory Calculations in Lithium-Sulfur Batteries.Molecules (Basel, Switzerland) · 2026Review
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Authors and funding
11 authors.
Funding
Abstract
The escalating demand for high-performance dielectric energy storage materials in pulse-power systems and portable electronics calls for polymer film capacitors with high discharged energy density and breakdown strength. Conventional polymers, however, suffer severe performance degradation under concurrent thermal and electrical stress, and existing reinforcement strategies-involving inorganic nanofillers or chemical crosslinking-often compromise flexibility, introduce interfacial defects, or involve complex processing. Herein, we demonstrate that incorporating a rigid mechanically interlocked molecule, specifically an octacationic homo[2]catenane, into a polyimide matrix yields robust, crosslink-like networks through strong [π∙∙∙π] electrostatic interaction between electron-rich aromatic units of polyimide and electron-deficient homo[2]catenane. This supramolecular network simultaneously enhances breakdown strength via densified chain packing and suppresses conduction loss by forming deep electron traps derived from the high electron affinity of homo[2]catenane. The optimized PI-HC
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