Decoupling Mechanical and Conductive Properties of Cellulose Ionogels for Flexible Electronics: A Review.

High-performance flexible electronics require soft materials that combine mechanical robustness with efficient ionic conduction. In conventional ionogels, however, these requirements often conflict: dense networks improve strength but reduce the free volume and mobility needed for ion transport. This review provides a critical overview of recent progress in cellulose-based ionogels, with emphasis on design principles for decoupling mechanical and conductive properties. We discuss how cellulose precursors, crosslinking architectures (hydrogen bonding, covalent networks, and metal-ion coordination), and processing histories determine gel structure and mechanical integrity. We then highlight strategies that mitigate the trade-off, including precursor engineering, phase-separated networks, double-network architectures, crystallization-induced reorganization, and anisotropic assembly. Representative applications in flexible sensors, flexible energy-storage devices, and soft actuators are also summarized. This review offers a practical framework for designing cellulose-based soft functional materials with robust mechanics and sustained ionic conductivity.