ArticleSmall methods2026
Plasma-Assisted Fabrication of Defect-Rich Tri-Phase NiRu Alloy/Carbon Shell Heterostructure with Ni-O-Ru Interfaces for Efficient and Durable Anion-Exchange-Membrane Water Electrolyzers.
Article in Small methods, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
This study presents a synergistic strategy combining plasma-assisted magnetron co-sputtering and thermal oxidation of a carbon shell to fabricate a self-supported FL-C@NiRu/NCNT@CC electrode with a tri-phase "NiRu alloy core-graphitic shell-Ni-O-Ru interfacial boundary" structure. Sub-nanometer-scale uniform alloying of Ni and Ru via radio-frequency/direct-current plasma magnetron co-sputtering enables precise modulation of metal electronic structure and interfacial charge-distribution, activating d-orbital coupling and interface-polarization. An in-situ conductive graphite-shell is deposited on alloy particles, followed by mild air thermal-oxidation, which thins the carbon shell, reconstructs boundary defects, and induces the formation of a Ni-O-Ru heterostructure. This enhances interfacial coupling and intrinsic oxygen-evolution-reaction (OER)/hydrogen-evolution-reaction (HER) activity. Consequently, the electrode exhibits excellent bifunctional electrocatalytic performance in alkaline media, with a HER overpotential of 75 mV and an OER overpotential of 324 mV at 100 mA cm
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