ArticleMacromolecular rapid communications2026
Synergistic Enhancement of Environmental Stress Crack Resistance and Mechanical Properties of HDPE via Reactive Blending-Induced Disulfide-Linked Covalent Networks.
Article in Macromolecular rapid communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Environmental stress cracking resistance (ESCR) remains a critical limitation for high-density polyethylene (HDPE), as conventional strategies to enhance ESCR often compromise mechanical performance or melt processability. Herein, a dynamic covalent network is constructed in HDPE via reactive melt blending using a disulfide-containing bismaleimide (DTBMI) crosslinker. Radical activation enables DTBMI to capture HDPE macroradicals, forming a dynamically crosslinked network without sacrificing thermoplastic processability. The introduction of 2 phr DTBMI significantly enhances ESCR, with the failure time (f
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