ArticleNature communications2026
Solar-driven peroxyacid group activation enables> 500 h stable hydroxyl-radical defluorination of industrial perfluorophenol wastewater.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Authors and funding
11 authors.
Funding
Abstract
Fluoroarenes persist in aquatic environments because aromatic delocalization and aqueous speciation suppress selective C-F bond cleavage, limiting both reductive activation and direct hole oxidation. Hydroxyl radicals (·OH) can mineralize these contaminants, yet near-neutral·OH generation typically relies on added oxidants or Fenton chemistry, creating chemical demand and secondary residues. Here we report a carboxyl-functionalized crystalline perylene diimide photocatalyst (Carboxyl-PDI) that produces ·OH via a catalytic carboxyl-peroxyacid cycle under visible light. Carboxyl-PDI delivers a 50.94% apparent quantum yield for ·OH at 600 nm, achieves complete defluorination of 100 mg L
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Registered trials
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