ArticleAngewandte Chemie (International ed. in English)2026
Hierarchically Porous Multivariate COF Aerogel With Enhanced Diffusibility and Tailored Functionality for Highly Efficient Bromine Sequestration.
Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Elemental bromine, owing to its inherently toxic, corrosive, and volatile nature, poses a great threat to the environment and public health. In this regard, although crystalline covalent organic frameworks (COFs) offer ordered porosity and tunable functionality, their powdered form often leads to aggregation, limited diffusibility, and poor processability. Transforming COFs into ultralight, mechanically robust, and easily processable aerogels overcomes these challenges by introducing hierarchical porosity, reduced density, and rapid mass transport pathways. Herein, we have strategically fabricated a series of multivariate covalent organic frameworks in the form of aerogels with high surface area, hierarchical porosity, and multiple binding sites for efficient sequestration of bromine in both vapor and solution phases. The multivariate aerogel shows a high Br
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